Warner Home Video

The quintessential (and firstBatman villain to star in the 1966 series, Frank Gorshin would end up playing The Riddler in all of the character’s appearances in the series except for a two-episode span during season two when John Astin stepped into the green tights.

Warner Home Video
Warner Home Video

SEASON 2 (EPISODES 45, 46)

Perhaps best known for playing Gomez Addams in The Addams Family, John Astin donned The Riddler’s costume for a short two-episode arc during Batman’s second season.

Warner Home Video
Warner Home Video

SEASON 1 (EPISODES 3, 4, 21, 22, 33, 34), SEASON 2 (EPISODES 17, 18, 27, 28, 37, 38, 39, 42, 43, 44), SEASON 3 (EPISODES 1, 4, 5, 20)

Burgess Meredith’s portrayal of The Penguin may be the most iconic of the entire series (at least in appearance). With his purple top hat, monocle, and long cigarette, Meredith’s Penguin appeared in more Batman episodes (20) than any other villain.

Warner Home Video
Warner Home Video

SEASON 1 (EPISODES 5, 6, 15, 16, 25, 26), SEASON 2 (EPISODES 21, 22, 37, 38, 39, 47, 48, 57, 58), SEASON 3 (EPISODES 10, 16, 17, 24)

Second only to Burgess Meredith as The Penguin, Cesar Romero appeared in Batman as The Joker in 19 episodes in total. Known for his bright green hair, stark white makeup, and wide smile, Romero’s Joker would become one of the show’s most memorable villains. The actor famously refused to shave his signature mustache and you can see it under the white face paint particularly well on the high-definition transfers included on this Blu-ray box set.

Warner Home Video
Warner Home Video

SEASON 1 (EPISODES 7, 8)

Appearing as Mr. Freeze for only two episodes during the show’s first season, George Sanders’s Mr. Freeze was quite low-tech compared to the getups that Otto Preminger and Eli Wallach would wear during season two. When he did eventually don his signature suit, Sanders looked more like an astronaut than a villain with super freezy powers.

Warner Home Video
Warner Home Video

SEASON 2 (EPISODES 19, 20)

Legendary, groundbreaking director Otto Preminger (Laura) took over the role of Mr. Freeze for two episodes during Batman’s second season and gave perhaps the most bizarre (and cool) performance of the three actors that would play the character.

Warner Home Video
Warner Home Video

SEASON 2 (EPISODES 59, 60)

Eli Wallach played the frigid villain for the final two episodes of season two. His Mr. Freeze, who discovered an instant ice formula, is easily the most mustache-twirlingly and villainous of the three versions. For many fans, his version is also the most memorable.

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